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Analysis of Fracture Toughness Mechanism in Ultra-fine-grained Steels.

Despite their transformative role in our society, oxide glasses remain brittle. Although extrinsic postprocessing techniques can partially mitigate this drawback, they come with undesirable side effects. Alternatively, topological engineering offers an attractive option to enhance the intrinsic strength and damage resistance of glass.

On the basis of this approach, we report here the discovery of a novel melt-quenched lithium aluminoborate glass featuring the highest crack resistance ever reported for a bulk oxide glass. Relying on combined mechanical and structural characterizations, we demonstrate that this unusual damage resistance originates from a significant self-adaptivity of the local atomic topology under stress, which, based on a selection of various oxide glasses, is shown to control crack resistance. This renders the lithium aluminoborate glass a promising candidate for engineering applications, such as ultrathin, yet ultrastrong, protective screens. The Supporting Information is available free of charge on the at DOI:. • Physical properties of as-prepared and compressed samples, X-ray diffraction spectrum of as-prepared glass, differential scanning calorimetry upscan of as-prepared glass, ATR-FTIR spectrum of as-prepared glass, homogeneity check using micro-Raman spectroscopy, Brillouin scattering spectra, nanoindentation curves, details of Raman deconvolution, 6Li and 7Li MAS NMR spectra, 11B and 27Al 3QMAS NMR spectra, and overview of crack resistance data for various oxide glasses (). Learn more about these metrics Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days. Duane Eddy Midi Files.

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